Continuous Spray Dispenser For Highly Corrosive and Other Low Compatibility Products

ABSTRACT

A spray dispensing device including a first chamber defined by a container, a bladder contained within the first chamber that houses a fluid composition (e.g., a bleach composition), and an actuator in fluid communication with the first chamber so as to allow dispensing of the fluid composition from the bladder when the actuator is actuated (e.g., pressed). A pressurized composition may be contained within a second chamber, which acts as a pressure control device. The pressure of the pressurized composition may be in a range of from about 70 psi to about 150 psi. An outlet valve may provide selective fluid communication between the pressure control device (i.e., the second chamber) and the first chamber.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of co-pending United States Pat.Application No. 17/343,527, filed on Jun. 9, 2021, which is acontinuation of United States Pat. Application No. 16/590,811, filed onOct. 2, 2019, which is a continuation of United States Pat. ApplicationNo. 15/261,766 filed on Sep. 9, 2016, which is now granted U.S. Pat. No.10,472,162, issued Nov. 12, 2019. The entire disclosures of the aboveapplication and patent are incorporated herein by reference.

FIELD OF THE INVENTION

The present disclosure relates to dispensing devices, particularly tohandheld dispensing containers for spraying cleaning compositions. e.g.,such as bleach. Although particularly suitable for dispensingcompositions including an oxidant or other corrosive and/or lowcompatibility component, other fluid compositions could also bedispensed from the device.

DESCRIPTION OF RELATED ART

Currently, bleach compositions are typically provided in jugs or similarcontainers that require the user to pour the desired amount of bleach.Some bleach containing products (e.g., toilet bowl cleaners) arepackaged in squeezable containers that allow a user to squirt a desiredamount of the product by squeezing the sides of the container. Whilebleach compositions are highly efficacious at cleaning, and killingmicrobes (e.g., sanitizing, disinfecting, and sterilizing), therecontinues to be a need for alternative, more convenient modes ofdispensing such compositions. Previous attempts to dispense suchcompositions through alternative mechanisms have been hampered by thepresence of oxidizing agents (e.g., typically hypochlorites and/orperoxides) within the composition, which are highly corrosive and/orotherwise incompatible with many materials.

BRIEF SUMMARY

One aspect of the present invention relates to a spray dispensing devicethat may dispense a fluid composition. In some embodiments, the fluidcomposition may be a cleaning or other composition including anoxidizing agent, or other corrosive agent that may corrode or otherwisecompromise components typically employed in spray mechanisms,containers, and the like. According to one embodiment, a spraydispensing device may include a first chamber defined by a containerhaving contoured sidewalls (e.g., a non-cylindrical container, e.g.,which may include a wide variety of shapes for ornamental purposes,enhanced gripping, or the like). The device may further include abladder contained within the first chamber, which bladder houses a fluidcomposition to be dispensed (e.g., an oxidizing bleach composition). Anactuator may be provided in fluid communication with the first chamberconfigured to dispense the fluid composition from the bladder uponactuation of the actuator. A second chamber may also be provided, whichacts as a pressure control device. A pressurized composition may becontained in the second chamber, e.g., at a pressure in a range of about70 psi to about 150 psi. An outlet valve may be provided, which providesselective fluid communication between the pressure control device andthe first chamber.

Such an outlet valve may be configured to provide a substantiallyconstant pressure within the first chamber, so as to apply asubstantially constant pressure against the bladder over the life of thespray dispensing device (which device may typically be disposable afterthe contents have been spent). Such a configuration may allow forcontinuous dispensing of the fluid composition so long as the actuatorremains actuated. Where substantially constant pressure is providedwithin the first chamber, the spray stream or aerosol of dispensed fluidmay advantageously be maintained at a substantially constant flow rateand pattern over the life of the spray dispensing device. In otherwords, the last portion of fluid composition dispensed from thecontainer may be dispensed with similar spray pattern and othercharacteristics as compared to the first portion of fluid compositiondispensed from the container. In addition, the described configurationmay also allow the container to be inverted, or rotated to any desiredorientation, while still maintaining the same dispensing characteristics(i.e., dispensing is not gravity dependent).

Another spray dispensing device may include a first chamber defined by acontainer, a bladder contained within the first chamber and housing afluid composition, and an actuator in fluid communication with the firstchamber configured to dispense the fluid composition from the bladderupon actuation thereof. A second chamber (e.g., also disposed within thecontainer) may be provided which acts as a pressure control device, anda pressurized composition may be contained within the second chamber.The pressurized composition may be selected from the group consistingof: air, nitrogen, carbon dioxide, nitrogen, inert components (e.g.argon) and combinations thereof. Any components of the pressurizedcomposition may be in solid, liquid or gaseous phases and anycombinations thereof (e.g. liquid nitrogen, carbon dioxide gas, solidcarbon dioxide, etc.). An outlet valve may provide selective fluidcommunication between the pressure control device and the first chamber,e.g., so as to selectively permit the pressurized composition to flowfrom the second chamber (i.e.. the pressure control device) into thefirst chamber as the fluid composition is dispensed, in order tomaintain a substantially constant pressure within the first chamber. Thespray dispensing device may be free of hydrocarbon propellants.

The elimination of the use of any hydrocarbon propellants reduces oreliminates the detrimental environmental effects associated with use ofsuch propellants in existing dispensing systems. In addition, in thepresent system the composition which may contain corrosive or strongoxidizing agents does not require being filled under pressure. Notworking with or handling a pressurized corrosive and/or oxidizingcomposition is a significant advantage during manufacturing because itis much safer to work with and reduces manufacturing complexity. Thepresent system instead provides a “bag-on-valve” or “bag-in-bottle”(used interchangeably herein) type dispensing system combined with aseparate second chamber that serves as a pressure control device, so asto provide the non-hydrocarbon pressurized composition into the firstchamber as needed. The pressurized composition employed mayadvantageously be air, nitrogen, carbon dioxide, or other relativelyenvironmentally inert component (e.g. in gaseous or liquid phase), whichis able to drive the fluid composition from the bladder upon the useractuating the actuator, as this pressurized composition flows throughthe outlet valve and into the first chamber.

Another embodiment is directed to a spray dispensing device that doesnot include an internal piston. The device may include a first chamberdefined by a container having non-linear sidewalls (e.g., where thechamber is non-cylindrical), in which the chamber has a transversecross-section that varies along a vertical axis of the first chamber.The lack of an internal piston allows the chamber to have any desiredshape, e.g., which may include contouring or other features forornamentation, improved grip, or other purposes within the central bodyportion of the sidewall of the container defining the first chamber. Byway of example, the central body portion of the sidewall of thecontainer and the first chamber may be narrowed in its central portion,and wider towards the top and bottom ends. Numerous other contouredshapes are also possible. Such a shape in the interior of the firstchamber is possible where the spray dispensing device does not rely on apiston movable within the first chamber to drive dispensing of the fluidcomposition from the dispensing device.

The device may further include a bladder contained within the firstchamber, housing a fluid composition, an actuator in fluid communicationwith the first chamber, a second chamber which acts as a pressurecontrol device, and a pressurized composition contained within thesecond chamber. The pressurized composition may comprise: air, nitrogen,carbon dioxide, inert components (e.g. argon) and any combinationsthereof. The pressurized composition may be in solid, liquid or gaseousphases and any combinations thereof. Any of the forgoing pressurizedcomposition materials may be in liquid or gaseous phase. An outlet valvemay provide selective communication between the second chamber (i.e.,the pressure control device) and the first chamber.

Further features and advantages of the present invention will becomeapparent to those of ordinary skill in the art in view of the detaileddescription of preferred embodiments below.

BRIEF DESCRIPTION OF THE DRAWINGS

To further clarify the above and other advantages and features of thepresent invention, a more particular description of the invention willbe rendered by reference to specific embodiments thereof which areillustrated in the drawings located in the specification. It isappreciated that these drawings depict only typical embodiments of theinvention and are therefore not to be considered limiting of its scope.The invention will be described and explained with additionalspecificity and detail through the use of the accompanying drawings inwhich:

FIG. 1 is a perspective view of an exemplary spray dispensing device;

FIG. 2 is a cut-away view of the spray dispensing device of FIG. 1 ;

FIG. 3 shows a user actuating the actuator on the spray dispensingdevice, so that the fluid composition is dispensed from the spraydispensing device onto a shower wall;

FIG. 4 is a cross-sectional view through the spray dispensing device ofFIG. 3 , with arrows showing flow of pressurized composition from thesecond chamber into the first chamber, and additional arrows showingapplication of forces that result in dispensing of the fluid compositionfrom the bladder and actuator as an aerosol;

FIG. 5 is a cross-sectional view similar to that of FIG. 4 , but showingan alternative configuration.

FIG. 6 is a block diagram showing an aspect of the present invention.

FIG. 7 is a block diagram showing another aspect of the presentinvention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS I. Definitions

Before describing the present invention in detail, it is to beunderstood that this invention is not limited to particularlyexemplified systems or process parameters that may, of course, vary. Itis also to be understood that the terminology used herein is for thepurpose of describing particular embodiments of the invention only, andis not intended to limit the scope, of the invention in any manner.

All publications, patents and patent applications cited herein, whethersupra or infra, are hereby incorporated by reference in their entiretyto the same extent as if each individual publication, patent or patentapplication was specifically and individually indicated to beincorporated by reference.

The term “comprising” which is synonymous with “including,”“containing,” or “characterized by,” is inclusive or open-ended and doesnot exclude additional, unrecited elements or method steps.

The term “consisting essentially of” limits the scope of a claim to thespecified materials or steps “and those that do not materially affectthe basic and novel characteristic(s)” of the claimed invention.

The term “consisting of” as used herein, excludes any element, step, oringredient not specified in the claim.

It must be noted that, as used in this specification and the appendedclaims, the singular forms “a,” “an” and “the” include plural referentsunless the content clearly dictates otherwise. Thus, for example,reference to a “surfactant” includes one, two or more surfactants.

The compositions described herein may provide sanitization,disinfection, or sterilization. As used herein, the term “sanitize”shall mean the reduction of contaminants in the inanimate environment tolevels considered safe according to public health ordinance, or thatreduces the bacterial population by significant numbers where publichealth requirements have not been established. By way of example, an atleast 99% reduction in bacterial population within a 24 hour time periodis deemed “significant” Greater levels of reduction are possible, as arefaster treatment times (e.g., within 1 minute), when sanitizing. As usedherein, the term “disinfect” shall mean the elimination of many or allpathogenic microorganisms on surfaces with the exception of bacterialendospores As used herein, the term “sterilize” shall mean the completeelimination or destruction of all forms of microbial life and which isauthorized under the applicable regulatory laws to make legal claims asa “sterilant” or to have sterilizing properties or qualities. Someembodiments of the present compositions provide for at least a 3 or morelog reduction in bacterial population within a designated time period. A3-log reduction is equivalent to at least a 99.9% reduction, a 4-logreduction is equivalent to at least a 99.99% reduction, a 5-logreduction is equivalent to at least a 99.999% reduction, etc.

Unless otherwise stated, all percentages, ratios, parts, and amountsused and described herein are by weight.

Numbers, percentages, ratios, or other values stated herein may includethat value, and also other values that are about or approximately thestated value, as would be appreciated by one of ordinary skill in theart. A stated value should therefore be interpreted broadly enough toencompass values that are at least close enough to the stated value toperform a desired function or achieve a desired result, and/or valuesthat round to the stated value. The stated values include at least thevariation to be expected in a typical manufacturing or formulationprocess, and may include values that are within 10%, within 5%, within1%, etc. of a stated value. Furthermore, the terms “substantially”,“similarly”, “about” or “approximately” as used herein represent anamount or state close to the stated amount or state that still performsa desired function or achieves a desired result. For example, the term“substantially” “about” or “approximately” may refer to an amount thatis within 10% of, within 5% of, or within 1% of, a stated amount orvalue.

Some ranges may be disclosed herein. Additional ranges may be definedbetween any values disclosed herein as being exemplary of a particularparameter. All such ranges are contemplated and within the scope of thepresent disclosure.

In the application, effective amounts are generally those amounts listedas the ranges or levels of ingredients in the descriptions, which followhereto. Unless otherwise stated, amounts listed in percentage (“%′s”)are in weight percent (based on 100% active) of the fluid composition.

Unless defined otherwise, all technical and scientific terms used hereinhave the same meaning as commonly understood by one of ordinary skill inthe art to which the invention pertains. Although a number of methodsand materials similar or equivalent to those described herein can beused in the practice of the present invention, the preferred materialsand methods are described herein.

II. Introduction

In an aspect, the present invention is directed to a spray dispensingdevice including a first chamber defined by a container (e.g., which mayinclude contoured, non-cylindrical sidewalls), a bladder containedwithin the first chamber that houses a fluid composition (e.g.. a bleachcomposition), and an actuator in fluid communication with the firstchamber (e.g., or more particularly, in fluid communication with theinterior of the bladder) so as to allow dispensing of the fluidcomposition from the bladder when the actuator is actuated (e.g.,pressed). A pressurized composition may be contained within a secondchamber, which acts as a pressure control device. The pressure of thepressurized composition may be in a range of from about 70 psi to about150 psi. An outlet valve may provide selective fluid communicationbetween the pressure control device (i.e., the second chamber) and thefirst chamber.

The present spray dispensing devices advantageously provide the abilityto deliver a fluid composition including an oxidizing agent, or otherfluid composition which may include a corrosive agent, or othercomponent exhibiting other incompatibility issues, as a continuous sprayaerosol. Such aerosol dispensing of bleach and similar compositions hasnot previously been possible as a practical matter. The claimed spraydispensing devices may provide the fluid composition prepackaged withinthe spray dispensing device (e.g., within the bladder thereof). Thedisclosed configuration ensures that the bleach or other fluidcomposition does not contact the interior of the container of the spraydispensing device, which provides several advantages, making delivery ofsuch a bleach aerosol or similar low compatibility fluid compositionpossible. In addition to providing a configuration where the fluidcomposition does not contact the interior of the container, there is nocontact between any propellant employed in dispensing the fluidcomposition and the fluid composition itself. Thus, dispensing of thepure fluid composition itself is possible.

In addition, in one embodiment of the invention no hydrocarbonpropellants (e.g., isopentane, propane, isobutane, pentane, butane,fluorinated hydrocarbons, and the like) are needed. For example, theemployed pressurized component (rather than a conventional propellant),as stored in the second chamber, may comprise: air, nitrogen, carbondioxide, nitrogen, inert components (e.g. argon) and any combinationsthereof. The pressurized composition may be in solid, liquid or gaseousphases and any combinations thereof. As the pressurized component doesnot contact the fluid composition itself (rather only the bladder),there is no risk of reactions, contamination, degradation, or the likethat may otherwise occur with traditional aerosol systems in which apropellant and fluid composition being dispensed are mixed with or oneanother or otherwise contact one another.

The disclosed dispensing devices also advantageously allow dispensingthe fluid composition even when the container is in an invertedposition, or any position in between inverted and a normal uprightorientation. Where dispensing does not rely on the inclusion of anyinternal piston, the sidewalls of the container may be other thancylindrical. For example, various contours are possible forornamentation, for enhanced grip, or for other purposes. Suchconfigurations also allow the second chamber which acts as the pressurecontrol device to be oriented as desired, and not necessarily in axialalignment with the longitudinal axis of the device, or with the bladder.In other words, in previous configurations, there has always been axialalignment with the various components in the spray dispensing system(i.e., all aligned with the longitudinal axis). In another embodiment ofthe invention, the pressure control device could be provided outside ofor separate from the dispensing device and could be attached/coupled tothe device immediately prior to use. Alternatively, the pressure controldevice may be coupled to the dispensing device and still be outside orseparate from the dispensing device. Alternatively, the pressure controldevice maybe inside the spray dispensing system, but not attached to theinterior of the dispensing device such that it may be created and/orfilled externally prior to being placed in the dispensing device. Inthis embodiment, the pressure control device may have an outlet valveattached to it so that is fully functionally prior to being placed intothe dispensing device. When the pressure control device has an outletvalve attached to the pressure control device, the container may becreated without an outlet valve attached to any of the container walls.The present configurations allow for the alignment and non-separablearrangement requirements to be eliminated, freeing the configurationfrom such necessary alignment and detachment/separation problems betweenthe dispensing container, the outlet valve and the pressure controldevice.

III. Exemplary Dispensing Systems

FIGS. 1-4 show an exemplary spray dispensing device 100 which may beprefilled (e.g.. during manufacture) with any desired fluid composition.In some embodiments, the fluid composition may include an oxidizingagent (e.g., one or more of hypochlorites, halogens, peroxides,hypochlorous acid, or the like). Examples of hypochlorites include, butare not limited to alkali metal hypochlorites (e.g.. sodiumhypochlorite, potassium hypochlorite, and the like, alkali earth metalhypochlorites (e.g., calcium hypochlorite, magnesium hypochlorite, andthe like). Combinations of hypochlorites may of course be employed. Anexample of a peroxide is hydrogen peroxide, although other peroxides mayalso be employed.

The spray dispensing device configurations disclosed herein may also beused for dispensing fluid compositions that include other componentsthat are corrosive or otherwise exhibit poor compatibility with metalsor other materials typically employed in an aerosol dispenser. The spraydispensing devices may also be used for dispensing fluid compositionsthat do not include any such low-compatibility or corrosive components.FIG. 2 is a cut-away view into the dispensing device 100, better showinghow the fluid composition 102 may be stored within an internal bladder104 disposed within first chamber 106 defined by container 108. Anactuator 110 may be provided, configured to selectively provide fluidcommunication with the interior of the bladder 104 within first chamber106. Actuator 110 may be configured to dispense the fluid composition102 from bladder 104 upon pressing or otherwise actuating actuator 110.

Actuator 110 may be any of a wide variety of mechanisms configured todispense fluid composition 102 from bladder 104, as will be appreciatedby those of skill in the art. Such actuator may be capable ofselectively dispensing the fluid composition 102 from bladder 104 uponthe consumer pressing a button or the like on actuator 110 to initiatedispensing. Such actuators will be apparent to those of skill in theart, and may be available from GUALA (Spinetta Marengo. Italy), AIROPACK(Waalwijk Netherlands), and other suppliers.

As perhaps best seen in FIG. 2 , a second chamber 112 may also beprovided, e.g., within container 108. separated from first chamber 106.Second chamber 112 acts as a pressure control device by which apressurized composition 114 contained within second chamber 112 may bereleased as needed into first chamber 106 through outlet valve 116,which provides fluid communication between the second chamber 112 andthe first chamber 106 when a pressure in first chamber 106 drops below apredetermined threshold value at which the outlet valve 116 isconfigured to permit one-way passage of pressurized composition 114. Forexample, the pressurized composition 114 within second chamber 112 maybe at a first pressure that is higher than the pressure within firstchamber 106. The outlet valve 116 may be configured to regulate flow ofthe pressurized composition 114 from second chamber 112 into firstchamber 106. so as to maintain a given second pressure within firstchamber 106 over the life of the spray dispensing device 100, until allfluid composition 102 has been dispensed. For example, by substantiallyconstant, it is meant that the pressure within the first chamber mayremain within 25%, within 20%, within 10%, or within 5% of a desiredtarget value (e.g., about 40 psi).

By way of example, the outlet valve 116 may be configured as a one-wayvalve that automatically allows flow of the pressurized composition 114from second chamber 112 when the pressure within the first chamber 106drops below a specified threshold value. In this way, pressurizedcomposition 114 from second chamber 112 is automatically delivered intofirst chamber 106 as needed to maintain first chamber 106 at the desiredpressure, without any input by the consumer. Such pressure in the firstchamber 106 may be selected by the manufacturer to provide a desiredspray or aerosol pattern when dispensing fluid composition 102, as thepressure of the first chamber 106 drives dispensing of the fluidcomposition 102 in bladder 104 upon actuation of actuator 110.

One advantage of providing the configuration with a pressurized firstchamber 106, and an internal bladder 104 connected to actuator 110,through which fluid composition 102 is dispensed is that fluidcomposition 102 may be dispensed even when the container 108 is in aninverted position, or any position in between inverted and a normalupright orientation as shown in the drawings. Furthermore, as will beappreciated, there is no requirement for a dip tube as is often foundwithin many spray dispensing devices. For example, in at least someembodiments, no dip tube that typically extends from the actuator 110into the reservoir of fluid composition 102, e.g., down to a bottom ofthe reservoir of fluid 102 is needed. This is because flexible bladder104 progressively collapses about fluid composition 102 and actuator 110as fluid composition 102 is dispensed, and the volume thereof in bladder104 decreases. Thus, even without such a dip tube, the configuration mayallow a very high fraction of fluid composition 102 to be dispensed overthe life of the spray dispensing container (e.g.. at least 90%, at least95%, at least 97%, at least 98%, or at least 99%.

In addition, the configuration may allow a relatively high fraction ofthe volume defined within container 108 to actually be filled with fluidcomposition 102 which can be dispensed therefrom. For example, thedispensable volume of fluid composition may be at least 50%, at least55%, at least 60%, at least 65%, at least 70%, at least 75%, at least80%, at least 85%, or at least 90% of the volume defined withincontainer 108. Such a configuration prevents a situation undesirable toconsumers, where a large appearing container 108 only holds fordispensing a relatively small volume of fluid composition. Such can befrustrating to consumers.

By way of example, the pressure within first chamber 106 may bemaintained at a pressure above atmospheric pressure (in order to providethe driving force needed to dispense the fluid composition from bladder104, out of device 100). Pressure in first chamber 106 may be in a rangefrom about 20 psi to about 70 psi, from about 25 psi to about 60 psi, orfrom about 30 psi to about 50 psi. In an embodiment, such pressures maybe relative to atmospheric pressure (i.e., psig).

The pressure within second chamber 112 may be provided as manufacturedat an initial value that is greater than the pressure maintained withinfirst chamber 106. For example, in an embodiment, the initial pressure(i.e., before dispensing any fluid composition 102) within secondchamber 112 may be from about 70 psi to about 150 psi, from about 80 psito about 150 psi, from about 80 psi to about 120 psi, or from about 100psi to 120 psi. As described above, the pressure values in the secondchamber may be psig.

In embodiments where a liquid pressurized composition is provided withinthe second chamber, substantially higher pressures may be needed tomaintain the liquid phase at temperatures typical for use and storage ofthe spray dispensing devices. Where a liquid pressurized component isemployed, the pressurized component 114 may be in the liquid phase asstored in the second chamber, and may undergo a phase change to gaseousform after or as it passes through the outlet valve 116 into the firstchamber (which is at a lower pressure). Such gaseous form of thepressurized component 114 will advantageously apply the desired pressureagainst the flexible collapsible bladder 104 storing fluid composition102 so as to drive dispensing of fluid composition 102 upon actuation ofactuator 110.

It will be apparent that the second chamber acts as a pressure controldevice, such that the actual pressure within the second chamber 112 mayprogressively decrease over the life of device 100, as pressurizedcomposition within second chamber 112 is released through outlet valve116 into first chamber 106. Thus, as the fluid composition 102 isdispensed, the pressure within second chamber 112 may progressivelydecrease as pressurized composition 114 is passed through outlet valve116 into first chamber 106, e.g., to maintain first chamber 106 at adesired pressure sufficient to force fluid composition 102 withinbladder 104 out of device 100 through actuator 110 in a desired spraypattern. The dispensing pattern may dispense the fluid composition 102as an aerosol of very small droplets. Dispensing a liquid bleachcomposition as such an aerosol is particularly advantageous, as no suchproduct has been commercially available to date.

By way of example, the pressurized composition 114 may include air,nitrogen, carbon dioxide, or combinations thereof. In an embodiment, thepressurized composition 114 may be provided in the second chamber inliquid phase. In other embodiments, it may be provided in gaseous phase.In one embodiment, no hydrocarbon propellants (e.g., isopentane,propane, isobutane, pentane, butane, fluorinated hydrocarbons, and thelike) are needed, and no direct contact of the fluid composition 102with the pressurized composition 114 need occur. In addition, it will beapparent from the above described structure that the pressurizedcomposition 114 remains within the container 108. and is not required tobe dispensed at all from the container 108. Such a configuration ofcourse also prevents release of the pressurized composition 114 into theatmosphere at all, as it remains sealed within the container 108, evenafter the spray dispensing device 100 has reached the end of its usefullife. If desired, such pressurized composition could be recovered andreused by collecting the spent spray dispensing devices, and recoveringthe pressurized component for reuse, or recycling, if desired. Thatsaid, because in this embodiment no hydrocarbon propellants havingquestionable environmental safety are employed, such will not typicallybe necessary, as the spent pressurized composition may be: air,nitrogen, carbon dioxide, nitrogen, inert components (e.g. argon) andany combinations thereof. The pressurized composition may be in solid,liquid or gaseous phases and any combinations thereof (e.g. liquidnitrogen, carbon dioxide gas, solid carbon dioxide, etc.). As described,the fluid composition 102 may advantageously be stored within bladder104, which may be formed from a material that is specifically selectedto be compatible with the particular fluid composition. For example,where the fluid composition includes an oxidizing agent, such as ahalogen, a hypochlorite, hypochlorous acid, hydrogen peroxide, anotherperoxide, or combinations thereof, the bladder may be formed from anethylene vinyl alcohol (EVA) material configured as a thin barrier film.Such EVA material may also be suitable for use with other fluidcompositions stored in bladder 104. Other bladder materials may ofcourse also be employed, so long as care is taken to ensure that theselected bladder material is compatible with the specific fluidcomposition 102 stored therein. In some embodiments, the interiorsurface of the bladder 104 could be coated with a barrier layer to allowan otherwise less compatible material to be used for the bladder 104. By“compatible”, it is meant that the bladder material contacting the fluidcomposition 102 does not result in significant degradation, corrosion,dissolution, or other attack of the bladder material by the fluidcomposition 102 to be dispensed. Similarly, it is meant that the bladdermaterial does not contaminate or otherwise alter the desired propertiesof the fluid composition 102 stored within the bladder 104. For example,a bladder material that inactivates a hypochlorite or other bleachcomposition would be undesirable where the fluid composition 102 beingdispensed is a hypochlorite or other bleach.

Because the configuration of the spray dispensing device 100 ensuresthat the fluid composition 102 does not directly contact the interior ofcontainer 108, the container may be fabricated from materials that areattacked or otherwise incompatible with the fluid composition 102 (e.g.,one or more metals). In an embodiment, the container may be made from aplastic material, such as polypropylene, polyethylene (including HDPE),polycarbonate, or combinations thereof. In another embodiment, thecontainer may be made from one or more metal materials. Both metal andplastic materials could also be employed (e.g., for different parts ofcontainer 108). Similarly, the actuator may be made from suitableplastic materials, including, but not limited to those identified above.Such may be preferred as the fluid composition will come into contactwith the at least some of the components of actuator 110, particularlywhere the fluid composition includes an oxidizing agent or corrosive orlow compatibility agent. Where there are not compatibility concerns withthe fluid composition and metal, at least some of the actuatorcomponents could be made of metal.

As is apparent from the structure described in conjunction with theFigures, no internal piston is needed within container 108. Because nointernal piston is needed (dispensing instead relies on the bag-on-valveconfiguration of bladder 104, actuator 110. and pressurized firstchamber 106), the container itself can have a contoured configurationnot possible with containers that rely on an internal piston fordispensing. For example, as seen in FIGS. 1-4 , the sidewalls 118 ofcontainer 108 may be non-linear, including a contoured, curvedconfiguration within the central body portion (or elsewhere) in sidewall118. FIGS. 1-4 show a configuration where the central body portion 120may be narrower in width than the adjacent upper and/or lower portions122, 124. respectively, of sidewall 118 of container 108. FIG. 4 showshow such contoured configurations allow the transverse cross-section ofthe first chamber 106 to vary along the vertical axis A of the chamber,due to the non-linear sidewall 118. Numerous other contoured shapes willbe apparent to those of skill in the art that may be employed, becauseno internal piston is needed. For example, a contour may be providedwhich facilities improved ergonomic gripping of container 108 within thehand of a consumer (e.g., see FIG. 3 ) facilitating easier dispensing.

As seen in FIGS. 2 and 4 , a plug or valve 126 may be provided in bottomwall 128. or elsewhere within second chamber 112. in order to allowcharging of the pressurized composition 114 into second chamber 112during manufacture. The pressurized composition 114 may thus be filledinto second chamber 112 during manufacture through a valve (e.g., aone-way valve), or a hole which is subsequently stopped with a plug.Alternatively, a solid carbon dioxide composition could be added to thesecond chamber and then sealed on the bottom to create a pressurizedcomposition without the need for filling the second chamber through avalve. Various other techniques for filling second chamber 112 will beapparent to those of skill in the art, and are within the scope of thepresent disclosure.

An alternative embodiment is shown in FIG. 5 . For example, as shown inFIG. 5 , bottom 128 may be sealed, e.g.. with no inlet for pressurizedcomposition 114. Rather, the composition (e.g.. liquid nitrogen and/orliquid carbon dioxide) could be introduced into second chamber 112during manufacture, followed by sealing of second chamber 112, as shown.For example, bottom wall 128 could be provided separate from sidewall118, to be welded or otherwise secured thereto in a sealed arrangement.In another embodiment, a plug 126′ (e.g., elastomeric, plastic, metal,or other material) could be inserted into an associated opening throughbottom wall 128. Where the plug is plastic or metal, the plug 126′(e.g., similar to plug 126) could be welded or otherwise permanentlysealed in place.

Such a configuration may be particularly suited for a pressurizedcomposition 114 that is initially charged into second chamber 112 inliquid a liquid form (e.g., liquid nitrogen and/or liquid carbondioxide). A solid form of such composition 114 may also be suitable(e.g., placement of dry ice (i.e., solid CO₂) or solid nitrogen intosecond chamber 112) for initial charging into second chamber 112. Oncecharged, the chamber 112 may be sealed (e.g., welding bottom wall 128and/or plug 126′ into place). Once charged, the composition 114 (e.g.,which may initially be in a solid or liquid phase) may undergo a phasetransition to the gaseous phase, providing the desired pressurizedcomposition 114 for regulated release through outlet valve 116 intofirst chamber 106. Where composition 114 is initially in solid or liquidphase, care should of course be taken to ensure the charged amount isappropriate to provide the desired pressure within second chamber 112once the initially solid or liquid composition 114 undergoes a phasechange to be in gaseous phase.

Referring to FIG. 6 , in one embodiment, the pressure control device 210is provided outside of or separate from the dispensing device 200. Thepressure control device could be attached/coupled to the deviceimmediately prior to use. Alternatively, the pressure control device 210may be coupled to the dispensing device 200 and still be outside orseparate from the dispensing device 200. Referring to FIG. 7 , the spraydispensing system or device 300 includes a wall 310 defining aninterior. A pressure control device 320 maybe inside the spraydispensing system 300, but not attached to the interior of thedispensing device 300 such that it may be created and/or filledexternally prior to being placed in the dispensing device 300. In oneembodiment, the pressure control device 320 may have an outlet valve 330attached to it so that it is fully functional prior to being placed intothe dispensing device 300. When the pressure control device 320 has anoutlet valve 330 attached to the pressure control device 320, thecontainer may be created without an outlet valve attached to any of thecontainer walls.

Several suppliers would have the capability to manufacture the device asdescribed herein (or components thereof), in light of the presentdisclosure. For example, AIROPACK, GUALA, and other suppliers would havethe capability to produce the container, bladder, actuator, outletvalve, and other components described herein, if presented with thepresent disclosure. Additional details of exemplary bag-on- valve andpressure control devices, features of which may be incorporated hereinare described in U.S. Pat. No. 8.292.121 and U.S. Publication Nos.2001/0002598 and 2014/0183229, each of which is herein incorporated byreference in its entirety.

The fluid composition 102 to be dispensed may be any conceivablecomposition capable of being dispensed through the described structure.In some embodiments, the fluid composition may be a cleaning compositionthat may include an oxidizing agent. Such compositions may often includeone or more surfactants. An organic or mineral acid (e.g.. to aid incleaning) may be included. One or more of a chelating agent, or one ormore other adjuncts selected from the group consisting of fragrances,dyes, preservatives, humectants, solvents, polymers, pH adjusters,solubilizers, and combinations thereof may also be provided.

The composition may have a viscosity so that it may readily be dispensedas described herein. Liquid compositions may have a viscosity of lessthan 10,000 cps, or less than 1,000 cps. It may also be possible todispense gel or foam compositions from the spray dispensing devicesdescribed herein, and such is within the scope of the disclosure. In oneembodiment, the foam or gel may be dispensed without the need for apropellant or with a very small amount of propellant (e.g less than 20%propellant by weight, less than 15% propellant by weight, less than 10%propellant by weight, less than 5% propellant by weight, less than 2%propellant by weight, etc.)

In an embodiment, e.g.. where the composition contains a hypochloritecomponent, the pH may be from about 8 to about 14. from about 9 to about13, or from about 10 to about 13 (about 8, about 9, about 10, about 11,about 12, about 13. or about 14. or any range defined between any suchvalues). A hypochlorite oxidizing agent may have increased stability atsuch elevated pH values. In other embodiments, and depending on theparticular components included in the fluid composition, the compositionmay have a pH from about 1 to about 8. or from about 4 to about 8 (about1, about 2, about 3, about 4, about 5, about 6. about 7, or about 8, orany range defined between any such values).

In one embodiment, the fluid composition may include one or moresurfactants. Examples include, but are not limited to sulfates,sulfonates, betaines, alkyl polysaccharides, (e.g., alkylpolyglycosides, also known as alkyl polyglucosides), amine oxides,tweens, alcohol ethoxylates, and combinations thereof. One or more ofthe selected surfactants may provide foam building characteristics. Thesurfactant concentration may be any desired concentration. Examples mayinclude up to 80%, up to 50%, up to 30%, up to 20%, or less than 10%,less than 5%, less than 4%, less than 3%, or less than 2% by weight,depending on the characteristics desired.

The surfactant(s) may include nonionic, anionic, cationic, ampholytic,amphoteric, zwitterionic surfactants, and mixtures thereof. A typicallisting of anionic, ampholytic, and zwitterionic classes, and species ofthese surfactants, is given in U.S. Pat. No. 3.929.678 to Laughlin. Alist of cationic surfactants is given in U.S. Pat. No. 4.259.217 toMurphy. Various alkyl polysaccharide surfactants are disclosed in U.S.Pat. No. 5.776.872 to Giret et al.; U.S. Pat. No. 5,883,059 to Furman etal.; U.S. Pat. No. 5,883,062 to Addison et al.; and U.S. Pat. No.5.906.973 to Ouzounis et al. U.S. Pat. No. 4,565,647 to Llenado. Variousnonionic surfactants can be found in U.S. Pat. No. 3,929,678 toLaughlin. Each of the above patents is incorporated by reference.

An organic acid (e.g.. citric acid), or relatively weaker mineral acid(e.g., phosphoric acid) may be included for cleaning. Where included,such an acid may be included in an amount of less than 5%, less than 4%,less than 3%, less than 2% (e.g., from 1% to 2%, or from greater than0.5% to about 1.5%).

Exemplary organic acid may include 2-hydroxycarboxylic acids or mixturesof two or more acids. Examples of such acids include, but are notlimited to, tartaric acid, citric acid, malic acid, mandelic acid,oxalic acid, glycolic acid, lactic acid, and acetic acid.

pH adjusters (e.g., sodium hydroxide, or another hydroxide), if present,may typically be included in an amount of less than 3%, less than 2%,less than 1% (e.g., from about 0.5% or greater than 0.5% to 1%). Foradjusting pH downward, any of the above described acids may also besuitable for use.

Solubilizers (e.g., to solubilize a fragrance or other oil), if present,may typically be included in an amount of less than 1%, less than 0.5%,less than 0.3% (e.g.. from about 0.01 % to 0.5%).

Dyes, fragrances, and/or preservatives, if present, may typically beincluded in an amount of less than 1%, or less than 0.5%, Oxidizingagents, or any other components mentioned herein may be present inamounts of less than 10%, less than 5%, less than 4%, less than 3%, lessthan 2%, less than 1%, less than 0.5%, or less than 0.25%. The fluidcomposition may be formulated as a ready-to-use composition (e.g., withless than 1%, less than 0.5%, or less than 0.25% oxidizing agent),although a concentrate formulation intended to be diluted (e.g., withwater) may also be possible.

Specific compositions may be provided for kitchen use, for bathroom use,or for other specific or general uses. In some embodiments, thecompositions may be effective at cleaning, and removing soils typicallypresent in showers and bathtubs, such as, but not limited to soap scum,hard water stains, mildew, etc. The composition could also be used inother cleaning environments, e.g.. such as kitchens, bathroom sinks,walls, etc. In a kitchen environment, the composition may be effectiveat cleaning and removing kitchen grease. The composition could besprayed on bathroom countertops, kitchen countertops, sinks, tables,stovetops, dishes, windows, mirrors, or floors, to name just a few.

Without departing from the spirit and scope of this invention, one ofordinary skill can make various changes and modifications to theinvention to adapt it to various usages and conditions. As such, thesechanges and modifications are properly, equitably, and intended to be,within the full range of equivalence of the following claims.

1. A spray dispensing device, comprising: (a) a container having a sidewall, the container comprising: (i) a first chamber defined by the sidewall; and (ii) a second chamber fluidly coupled to the first chamber,the second chamber being inside of the container and not attached to aninterior of the spray dispensing device; (b) a flexible bladdercontained within the first chamber and configured to hold a fluidcomposition, wherein the flexible bladder is formed of a materialcompatible with the fluid composition; (c) an actuator, formed of amaterial that is compatible with the fluid composition, in fluidcommunication with the flexible bladder and configured to dispense thefluid composition from the flexible bladder upon actuation of theactuator; and (d) an outlet valve coupled to the second chamber so thatthe second chamber is fully functional prior to being placed into thedispensing device; wherein the fluid composition does not directlycontact an interior surface of the container; wherein the first chamberis configured to have a first pressure and the second chamber isconfigured to have a second pressure, the second pressure being greaterthan the first pressure; and wherein upon actuation of the actuator, thecontainer is configured to dispense the fluid composition from theflexible bladder while the second chamber fluidly communicates with thefirst chamber through the outlet valve.
 2. The spray dispensing deviceof claim 1, wherein the second chamber houses a pressurized compositionat a pressure in the range from about 70 psi to about 150 psi.
 3. Thespray dispensing device of claim 2, wherein the pressurized compositionis selected from the group consisting of air, nitrogen, carbon dioxide,argon and combinations thereof.
 4. The spray dispensing device of claim1, wherein the first chamber maintains a substantially constant pressureof about 25 psi to about 60 psi while the fluid composition is dispensedfrom the flexible bladder over a life of the spray dispensing device. 5.The spray dispensing device of claim 1, wherein a constant pressurewithin the first chamber is maintained in the range of about 20 psi toabout 70 psi.
 6. The spray dispensing device of claim 1, wherein theoutlet valve is configured to allow a pressurized composition in thesecond chamber to flow to the first chamber, wherein the pressurizedcomposition remains in the container.
 7. The spray dispensing device ofclaim 1, wherein the fluid composition comprises an oxidant and theinterior surface of the container comprises a metal.
 8. The spraydispensing device of claim 1, wherein the fluid composition includes oneor more oxidizing agents selected from the group consisting of halogens,hypochlorites, hypochlorous acid, hydrogen peroxide, other peroxides,and combinations thereof.
 9. The spray dispensing device of claim 1,wherein the interior surface of the container is incompatible with thefluid composition disposed within the flexible bladder.
 10. The spraydispensing device of claim 1, wherein the second chamber contains apressurizing composition.
 11. (canceled)
 12. The spray dispensing deviceof claim 10, wherein the pressurized composition comprises a liquidphase or a solid phase.
 13. The spray dispensing device of claim 1,wherein the container is made from a plastic material selected from thegroup consisting of polypropylene, polyethylene, polycarbonate, andcombinations thereof.
 14. The spray dispensing device of claim 1,wherein the flexible bladder comprises an ethylene vinyl alcohol barrierfilm.
 15. A spray dispensing device, comprising: (a) a container havinga non-linear side wall that has a curved exterior surface spanning alongat least a portion of the longitudinal axis of the container, wherein atransverse cross-section of the container varies along the longitudinalaxis of the container, the container comprising: (i) a first chamberhaving a first pressure; and (ii) a second chamber fluidly coupled tothe first chamber and configured to hold a pressurized compositionhaving a second pressure, the second chamber being provided separatefrom the dispensing device and coupled to the dispensing device prior touse; and (b) a flexible bladder housed within the first chamber andconfigured to contain a fluid composition; (c) an actuator in fluidcommunication with the flexible bladder and configured to dispense thefluid composition from the flexible bladder upon activation; and (d) anoutlet valve positioned between the first chamber and the secondchamber; wherein the second pressure is greater than the first pressure;wherein the pressurized composition does not contact the fluidcomposition as the pressurized composition flows into the first chamberfrom the second chamber through the outlet valve; wherein upon actuationof the actuator, the container is configured to dispense the fluidcomposition from the flexible bladder while the second chamber fluidlycommunicates with the first chamber through the outlet valve. 16.(canceled)
 17. The spray dispensing device of claim 15, wherein thepressurized composition comprises a liquid phase or a solid phase. 18.The spray dispensing device of claim 15, wherein the fluid compositionincludes a bleach composition and the flexible bladder is formed of amaterial compatible with the bleach composition.
 19. The spraydispensing device of claim 15, wherein the first chamber maintains asubstantially constant pressure of about 25 psi to about 60 psi whilethe fluid composition is dispensed from the flexible bladder over a lifeof the spray dispensing device.
 20. A spray dispensing device,comprising: (a) a container having a side wall, the containercomprising: (i) a first chamber having a first pressure; and (ii) asecond chamber fluidly coupled to the first chamber and configured tohold a pressurized composition having a second pressure, the secondchamber being inside of the container and not attached to an interior ofthe spray dispensing device; and (b) a flexible bladder housed withinthe first chamber and configured to contain a fluid composition, thefluid composition including an organic acid; (c) an actuator in fluidcommunication with the flexible bladder and configured to dispense thefluid composition from the flexible bladder upon activation; and (d) anoutlet valve positioned between the first chamber and the secondchamber; wherein the second pressure is greater than the first pressure;wherein the pressurized composition does not contact the fluidcomposition as the pressurized composition flows into the first chamberfrom the second chamber through the outlet valve; and wherein uponactuation of the actuator, the container is configured to dispense thefluid composition from the flexible bladder while the second chamberfluidly communicates with the first chamber through the outlet valve.21. The spray dispensing device of claim 20, wherein the organic acid isselected from the group comprising tartaric acid, citric acid, malicacid, mandelic acid, oxalic acid, glycolic acid, lactic acid, and aceticacid.
 22. The spray dispensing device of claim 1, wherein the fluidcomposition includes an organic acid selected from the group comprisingtartaric acid, citric acid, malic acid, mandelic acid, oxalic acid,glycolic acid, lactic acid, and acetic acid.